October 21, 1999 | 0 comments

How is caffeine removed to produce decaffeinated coffee?

 

"The third approach, supercritical carbon dioxide decaffeination, is very similar to the direct solvent methods, except that in this case the solvent is carbon dioxide. High-pressure vessels (operating at roughly 250 to 300 times atmospheric pressure) are employed to circulate the carbon dioxide through a bed of premoistened, green coffee beans. At such pressures, carbon dioxide takes on unique, 'supercritical' properties that enhance its usefulness as a solvent. Supercritical carbon dioxide has a density like that of a liquid, but its viscosity and diffusivity are similar to those of a gas. These attributes significantly lower its pumping costs. Carbon dioxide is a popular solvent because it has a relatively low pressure critical point, and it is naturally abundant. The caffeine-rich carbon dioxide exiting the extraction vessel is either channeled through a bed of activated charcoal or through a water 'bath' tower to absorb the caffeine. The carbon dioxide is then recirculated back to the extraction vessel. Supercritical carbon dioxide decaffeination is capital-cost intensive, but it offers very good yields. It typically can extract 96 to 98 percent of the caffeine originally present in the beans."



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