Metal Oxide Chips Show Promise as Transistors

Materials that flip from insulator to conductor could make more energy-efficient transistors, although the metals are not yet close to competing with silicon















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Some point to Schuller’s work as evidence that metal oxides will never make fast switches, because heating effects are usually quite slow. But Ramanathan says that his own measurements on vanadium oxide demonstrate that the phase transition is quite fast — less than a few nanoseconds — and that it should not hinder applications.

Some physicists are finding further examples of potentially useful materials. Bernhard Keimer at the Max Planck Institute for Solid State Research in Stuttgart, Germany, alternates thin layers of metal oxides to form composites that often turn out to have serendipitous properties. His group layered conducting lanthanum nickelate and insulating lanthanum aluminate and found that the composite underwent a transition between the two properties.

The highest phase-transition temperature for the composite was 150 kelvin above absolute zero — too low for practical applications. But the group is now trying to replicate the phenomenon in other materials that might have higher transition temperatures.

Sandip Tiwari, an applied physicist at Cornell University in Ithaca, New York, acknowledges that metal oxides are not yet close to competing with silicon. But given recent progress, he feels that researchers need to start trying to implement them in devices. That way, he says, all the properties needed for a good transistor will be developed in tandem. “If you just look at whatever property is your favorite, you won’t get them all.”

This article is reproduced with permission from the magazine Nature. The article was first published on March 6, 2013.



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  1. 1. Acoyauh2 01:32 PM 3/7/13

    I'm not clear on what this means. Metal oxide transistors are not new at all.

    CMOS (Complementary metal-oxide semiconductor) technology has been commercially available since the sixties/seventies, and the more sophisticated MOSFET (Metal-Oxide field effect transistors) not far behind, with much lower power consumption and high resistance to interference (or noise).

    Although the general tone of the article suggests MOS is being invented now, I assume the actual work is about something else - higher integration? Better performance? Cannot tell for sure from this piece.

    "But given recent progress, he feels that researchers need to start trying to implement them in devices" Heh, I've built CMOS and MOSFET based devices since the 80's - do I get a Nobel?

    NOT a good article here, sorry.

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  2. 2. jtdwyer in reply to Acoyauh2 02:41 PM 3/7/13

    "... addressed a fabrication challenge by growing a thin film of samarium nickelate on top of a substrate made of silicon and silicon dioxide."

    The article seems to be attempting to discuss the use of rare-Earth element oxides rather than more common aluminum or poly-silicone to fabricate circuits.

    On a related subject, what ever happened to silicone-on-sapphire as a promising 'new' substrate material? These new, rare metal oxides couldn't fall into similar cost and implementation rabbit holes, could they?

    Besides, it sounds like we'd have to warm up our computers on those cold winter mornings...

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  3. 3. lamorpa in reply to Acoyauh2 03:01 PM 3/7/13

    Your hubristic suggestion that the semiconductor researchers at Harvard University never heard of CMOS makes you the obvious fool. Between them and you, I have a guess who misunderstands the article.

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  4. 4. jtdwyer in reply to lamorpa 03:33 PM 3/7/13

    No doubt the researchers know that they're still producing CMOS circuits - but this seems to have been lost in translation by the author of this report. IMO, Acoyauh2's comments regarding this article are accurate and valid - making you the obvious, well, author's dupe...

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  5. 5. Acoyauh2 in reply to lamorpa 03:45 PM 3/7/13

    Bad hair day, huh?

    I'm sure the scientists are aware of last century's CMOS tech, and that they're probably either trying to improve it or seeking other alternatives.
    However, that is not what the article says, and that's what my comment refers to. The article suggests they're trying to invent metal oxide semiconductors, which is, to say the least, misleading.

    Relax, have a break, have a chocolate, or something that improves your mood...

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  6. 6. jtdwyer in reply to jtdwyer 03:47 PM 3/7/13

    Actually, I'm likely in error referring to the fabrications mentioned in the article as CMOS - MOSFET, as Acoyauh2 implies, is probably a more applicable description, if not precisely accurate.

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  7. 7. lamorpa in reply to Acoyauh2 04:14 PM 3/7/13

    Nice try, but no. The article states they're trying to invent metal oxide based semiconductors, not just oxide insulators on silicon (It's in the first sentence). I though you said you knew what your were talking about.

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  8. 8. jtdwyer in reply to lamorpa 06:32 PM 3/7/13

    The author says nothing about "trying to invent" anything anywhere, and in CMOS & MOSFET integrated circuits the metal oxides form the conducting circuits, not insulators. As I understand, doped silicon in those devices provides the semiconducting/semi-insulating gated circuit function.

    The inset illustration, "GO WITH THE FLOW", can help explain what the author is trying to describe. In the new devices, a thin layer of metal oxide on an insulating silicon substrate provides the semiconducting gated circuit function.

    However, even here the illustration states:
    "Metal oxide transistors have the potential to consume less power than silicon ones, because switching does not require the atoms to be relocated."

    I have no idea what atoms ever get relocated in any form of transistor - I think this is additional misinformation...

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  9. 9. jtdwyer in reply to jtdwyer 07:14 PM 3/7/13

    As best I can guess from this report _and_ the research report abstract,
    http://www.nature.com/nature/journal/v487/n7408/full/nature11296.html
    - the new switches consume less power because the electrons don't have to travel as far to produce a current flow, due to some quantum state phase transition effect.

    A _very_ important feature - incredibly, not even mentioned in this article - is that the nature of this switch makes it state persistent. In other words, these circuits could be used to produce low power non-volatile memory!

    As Acoyauh2 stated initially:
    "NOT a good article here, sorry."

    P.S. the enlarged inset illustration is located at
    http://www.nature.com/polopoly_fs/7.9335.1362498861!/image/metal-oxides.jpg

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  10. 10. Gizmo in reply to jtdwyer 07:22 PM 3/7/13

    Actually, no. The metal oxides in CMOS and MOSFET devices are not conductors. The MOS in MOSFET refers to the stack of layers forming the gate: a metal layer on top of a layer of Si02 on top of the semiconductor channel that actually carries current when the device is switched on. CMOS stands for Complementary metal oxide semiconductors refering to the fact that such devices use MOSFET transistors of both P and N types. This article is about research into using metal oxides AS semiconducting matrerials.

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  11. 11. vapur 08:57 PM 3/7/13

    A couple grammatical mistakes in the article:

    1) Commonest - should be "more common" or "most common", not "commoner" and "commonest."

    2) The subheading says, "the metals are not yet close to 'completing' with silicon." I believe that should say, "competing."


    Aside from those issues, I would like to see one of these theoretical applications actually be put use in the real world, not just as a lab result.

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  12. 12. jtdwyer in reply to Gizmo 09:04 PM 3/7/13

    Thanks for the correction - I was confusing the terms conducting metal and metal oxides with the dielectric (silicon dioxide) insulating layer.

    That being said, I did understand that the article was describing attempts to use special rare-Earth element oxides as semiconductors, rather than doped silicon.

    If you understand the following statements made in the article, _please_ explain:
    "Metal oxide transistors have the potential to consume less power than silicon switches, because the phase transition frees electrons from their localized state near each atom, without moving them through the bulk material. By contrast, silicon switches work by pulling electrons through the material to a channel where they conduct current (see ‘Go with the flow’)."
    and
    "Metal oxide transistors have the potential to consume less power than silicon ones, because switching does not require the atoms to be relocated."
    Please see
    http://www.nature.com/polopoly_fs/7.9335.1362498861!/image/metal-oxides.jpg

    Also, what do you think of an article that fails to mention that the switch being described is persistent? Please see
    http://www.nature.com/nature/journal/v487/n7408/full/nature11296.html

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  13. 13. lamorpa in reply to Gizmo 11:55 AM 3/8/13

    Yes, Gizmo. I'm sad to see a comment (not yours) where someone is criticizing the accuracy of the facts in the article (incorrectly) and providing incorrect information of their own. Metal–oxide–semiconductor refers to the structure of certain (field effect) transistors, with a metal gate electrode placed on top of an oxide _insulator_, on top of a semiconductor material. That is what CMOS is.

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  14. 14. jtdwyer in reply to lamorpa 03:20 PM 3/8/13

    lampora,
    Does CMOS switching "require the atoms to be relocated" as stated in the article?

    Please explain the article's statements:
    "Metal oxide transistors have the potential to consume less power than silicon switches, because the phase transition frees electrons from their localized state near each atom, without moving them through the bulk material. By contrast, silicon switches work by pulling electrons through the material to a channel where they conduct current (see ‘Go with the flow’)."
    and (especially)
    "Metal oxide transistors have the potential to consume less power than silicon ones, because switching does not require the atoms to be relocated."

    It is the misinformation and missing information that confuse even somewhat knowledgeable readers and cause them to search the provided incomplete information (in vain) for more complete understanding. That is, in the case of critical readers...

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  15. 15. jtdwyer in reply to lamorpa 03:27 PM 3/8/13

    BTW - no one ever 'hubristically' suggested that the researchers "never heard of CMOS" - except when you were 'hubristically' 'putting words into the mouth' of Acoyauh2:
    "Your hubristic suggestion that the semiconductor researchers at Harvard University never heard of CMOS..."

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  16. 16. peterbrm in reply to jtdwyer 02:10 AM 3/9/13

    The article states that "electrons near atoms" are freed up to move. So it is the electrons that are moving.

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