These complex molecules filter down into the lower atmosphere and eventually combine to produce an orange smog.
A separate layer of haze is found at a much higher altitude of 400-500 km and can be seen at the limb of the moon, apparently detached from the rest of the atmosphere.
This haze was thought to represent the ceiling of Titan's 'middle atmosphere' circulation which extends from pole to pole in one giant cell, but new results from Cassini suggest otherwise.
The change in solar heating was reflected by a rapid reversal in circulation direction in Titan's single pole-to-pole atmospheric cell, with an upwelling of gases in the summer hemisphere and downwelling in the winter hemisphere.
"Even though the amount of sunlight reaching the south pole was decreasing, the first thing we saw there during the six months after equinox was actually an increase in temperature at altitudes of 400-500 km, as atmospheric gases that had been lofted to these heights were compressed as they subsequently sank into a newly forming southern vortex," says Dr Nick Teanby from the University of Bristol, UK, and lead author of the study reported in the journal Nature.
"This heating effect is the same one that causes compressed air in a bicycle pump to heat up, and provided the smoking gun that the change in seasons was underway."
Cassini's instruments found that these gas molecules were sinking through the atmosphere at a rate of 1-2 millimetres per second.
Dr Teanby's team conclude that for the enrichment and motion to be seen throughout these altitudes, the actual source of the complex gas molecules must be higher still, and that the detached haze layer cannot signal the top of the atmospheric circulation cell.
The new observations instead suggest that these complex haze molecules are produced higher up, but that when they drop down to the 400-500 km level, a change in the character of the haze takes place, perhaps as individual particles clump together.
"It's impressive to see such dramatic solar-driven seasonal changes on a world where the sunlight is nearly a hundred times weaker than it is on Earth," adds Dr Teanby.
"Since a year on Titan is nearly 30 Earth years long, for the atmosphere to change over a period of just six months is extremely rapid."
"Models have predicted this change in Titan's atmospheric circulation for nearly 20 years, but Cassini has provided the first direct observations of it actually happening," says Nicolas Altobelli, ESA's Cassini project scientist.