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First "Buckyball" Molecules Created from Boron

Chemists have made the famous soccer ball–shaped molecule using a new element that allowed an unexpected atomic arrangement
buckyball


Clusters of 40 boron atoms form a hollow cage similar to the carbon buckyball.
Credit: WANG LAB/BROWN UNIVERSITY

Originally posted on the Nature news blog

Just in time for the World Cup final, researchers have succeeded in building the first ‘buckyballs’  made entirely from boron atoms. Unlike true, carbon-based buckyballs, the boron molecules are not shaped exactly like soccer balls.  But this novel form of boron might lead to new nanomaterials and could find uses in hydrogen storage.

Robert Curl, Harold Kroto and Richard Smalley found the first buckyball — or buckminsterfullerene — in 1985. The hollow cage, made of 60 carbon atoms arranged in pentagons and hexagons like a soccer ball, got its name from the US architect and engineer Richard Buckminster Fuller, who used the same shapes in designing his domes. The discovery opened the flood gates for creating more carbon structures with impressive qualities, such as carbon nanotubes and the single-atom-thick graphene. Since then, material scientists have also searched for buckyball-like structures made of other elements.

In 2007, Boris Yakobson, a material scientist at Rice University in Houston, Texas, theorized that a cage made of 80 boron atoms should be stable. Another study published just last week predicts a stable structure with 36 boron atoms.

Publishing today in Nature Chemistry, a team led by Lai-Sheng Wang, a chemist at Brown University in Providence, Rhode Island, has become the first to see such a beast — although its structure is slightly different from that predicted. The researchers call their 40-atom molecule borospherene. It is arranged in hexagons, heptagons and triangles.

“We predicted the possibility of B80 fullerene, and now, seven years after, it is remarkable to see experimental evidence,” says Yakobson. “Especially as it is not what any of the theoretical calculations predicted.”

Wang’s team found the structure while looking for analogues of graphene made of boron. They found that clusters of 40 boron atoms seemed to be unusually stable, but they didn’t know what form these clusters were taking. Further calculations and experiments revealed that they had made two stable structures — one an almost flat molecule, the other a hollow, ball-like structure made of tesselated shapes, similar to the carbon buckyball.

In addition to having a less elegant shape, the borosphene balls form a different type of internal bond from their carbon counterparts. This makes them difficult to use as isolated building blocks as they have a tendency interact with each other, but this reactivity may make boron buckyballs good for connecting in chains. It also makes the balls capable of bonding with hydrogen, which the team says could make them useful in hydrogen storage.

Boron is not the first element after carbon to get buckyballed, but the result may be the closest analogue to the carbon variety. Scientists have formed buckyball-like structures out of uranium-based and silicon-based compounds, mutli-walled boron nitride and molybdenum disulphide structures and smaller single-element cages of goldtin and lead. But only boron seems to match the large hollow cage and  symmetry of the original carbon buckyball, says Yakobson.

This article is reproduced with permission and was first published on July 13, 2014.

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