Secrets of Fracking Fluids Pave Way for Cleaner Recipe

Disclosure of the chemicals used in hydraulic fracturing could empower green chemistry

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The myriad liquid concoctions used in hydraulic fracturing make for quite a recipe book. Since January 2011, FracFocus, an online chemical-disclosure registry, has assembled a list of the mixtures used at more than 52,000 oil and gas wells across the United States. In these data, geochemist Brian Ellis sees opportunity. He plans to mix different chemicals into oil- and gas-rich shale rock inside a pair of high-pressure chambers that he is building. This will allow him to explore the reactions that occur when these ‘fracking’ fluids are injected deep underground.

The fluids, which are mixed with sand, are predominantly water, laced with 1% ‘special sauce’. The recipes for that fraction — a mixture that includes acids, solvents and corrosion inhibitors — were until the last few years secrets guarded by the companies that seek to penetrate shale formations to release stores of fossil fuels. But in the face of widespread concern about water contamination, 21 US states have adopted mandatory disclosure rules for the mixtures, making it easier for scientists such as Ellis, of the University of Michigan at Ann Arbor, to assess their impacts.

Much of the data end up in registries such as FracFocus, which is overseen by state energy and water organizations. “There are still a lot of bugs, but the vast majority of companies are now disclosing their chemicals,” says Scott Anderson, a senior policy adviser for the Environmental Defense Fund in Austin, Texas, which advocates for greener fracking procedures.

More than 500 companies have reported data to FracFocus so far. Academic researchers, advocacy groups and companies are now poring over those recipes to assess their toxicity in the hope of narrowing them down to a group of environmentally acceptable ones — and perhaps spurring the synthesis of even greener alternatives.

The boom in the disclosure of fracking-fluid components has occurred despite the fact that the federal government has yet to weigh in with its own rules. The Department of the Interior has proposed requiring the disclosure of chemicals used during hydraulic-fracturing operations on public lands, but much of the current oil and gas development is taking place on private land. Many companies are volunteering the information anyway, even in states that have no disclosure requirements. And companies that do the hydraulic fracturing, such as Halliburton and Baker Hughes, both based in Houston, Texas, are developing their own chemical-assessment programs in an apparent effort to address public concerns and reduce their environmental footprint.

The data in these registries, although increasingly abundant, remain incomplete, unconsolidated and difficult to compare. The European Union is phasing in a unified chemical-regulation program that governs reporting across all commercial sectors. Energy companies operating in the North Sea, for example, must all play by the same rules and abide by strict reporting requirements. But in the United States, the regulations on chemical reporting remain a mixture of state and national policies that vary by industry.

Even in states with disclosure laws, companies can omit information in the interests of protecting intellectual property. For example, a subsidiary of ExxonMobil, based in Irving, Texas, declined to list the components of a gelling agent — used to help to suspend sand in water — at one of its wells in Wyoming, calling the information a “trade secret”.

The result is that companies are still operating under their own risk assessments and not disclosing all of the information that might be needed for independent verification. “If everybody has a different definition of what is hazardous and doesn’t fully disclose the chemicals they use, then it is going to be awfully difficult to compare,” says Lauren Heine, co-director of Clean Production Action, an advocacy group based in Somerville, Massachusetts.

Heine’s group is sifting through company disclosures to perform a risk assessment on the most commonly used chemicals. The effort is designed to provide a single point of comparison so that scientists, industry and the public can make informed decisions about which chemicals are best.

Daniel Durham, who heads a chemical-assessment program at the Houston-based energy company Apache, says that although Heine’s effort is promising, companies do not need to wait. The US Environmental Protection Agency (EPA) already maintains its own public registry of preferred chemicals for various industrial processes. Companies that want to register their chemicals provide the EPA with toxicity and environmental-assessment data; the registry also allows companies to keep certain data confidential if intellectual property is involved.

The upshot is a growing — albeit incomplete — list of preferred chemicals that companies such as Apache can choose from as they design their fracking fluids. A company that wants to avoid using a solvent such as ethylene glycol monobutyl ether, for example — used to reduce viscosity but possibly toxic to the endocrine system — could look through the EPA list for alternatives. “It’s a very good road map to green chemistry,” Durham says.

Eventually, Durham hopes that researchers will help to develop novel chemicals that could be used to make the entire hydraulic-fracturing process cleaner and more efficient. Scientists such as Ellis could play an important part.

Ellis wants to know whether fracking fluids are contributing to geochemical reactions within the shale rock that might free up potentially dangerous metals and radionuclides, such as arsenic, barium, strontium and uranium. These elements are often found in trace concentrations in the waste water produced by oil and gas companies, but can also be found naturally in groundwater. Ellis eventually hopes to help companies to select better chemicals that would minimize the potential for contamination and the need for waste-water treatment. But for now, he says, he is focused on the basic science. “Fundamentally, I just want to understand those reactions a little better.”

This article is reproduced with permission from the magazine Nature. The article was first published on September 11, 2013.

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