



Researchers coax self-assembling materials into flowers, corals and other complex shapes
By Luciana Gravotta | May 19, 2013 | 6
The bouquet in this scanning electron microscope image measures about 50 micrometers across. Researchers used simple starting materials—barium chloride (a salt) and sodium silicate (glass)—that self-assemble into crystals....[More]
The bouquet in this scanning electron microscope image measures about 50 micrometers across. Researchers used simple starting materials—barium chloride (a salt) and sodium silicate (glass)—that self-assemble into crystals. The materials are in solution and will grow into crystals whose shapes are sculpted by environmental conditions such as temperature, acidity and the amount of carbon dioxide. [Less] [Link to this slide]
Spiky flowers grown on a base of budded globs show off the researchers’ ability to design complex forms using this new technique. Previous attempts to grow 3-D microstructures involved setting up the initial conditions and then letting the process unfold....[More]
Spiky flowers grown on a base of budded globs show off the researchers’ ability to design complex forms using this new technique. Previous attempts to grow 3-D microstructures involved setting up the initial conditions and then letting the process unfold. This is the first time researchers were able to design specific structures. By investigating precisely which conditions molded each shape, they were able to develop a sequence of environmental parameters that would sculpt complex structures such as this one. [Less] [Link to this slide]
The structures form on the surface of a submerged glass plate. As external carbon dioxide flows into the system, it begins to dissolve into the solution, creating a gradient: more carbon dioxide near the surface than at the bottom....[More]
The structures form on the surface of a submerged glass plate. As external carbon dioxide flows into the system, it begins to dissolve into the solution, creating a gradient: more carbon dioxide near the surface than at the bottom. The salt and glass molecules are very sensitive to this environmental cue, so how they grow will depend on depth. Stems form near the solution’s surface, cones at mid-depth and coral folds at its bottom. [Less] [Link to this slide]
These flowers grown in thin vases are made one piece at a time: First the vases, then the stems and finally a short burst of carbon dioxide that induces the stems to bloom into flowers....[More]
These flowers grown in thin vases are made one piece at a time: First the vases, then the stems and finally a short burst of carbon dioxide that induces the stems to bloom into flowers. The materials are very responsive to even minute changes in the environmental conditions, making each flower unique. As the materials come out of solution, they change the carbon dioxide level in their immediate vicinity and thus the shapes of their blooming neighbors. [Less] [Link to this slide]
The pleated petals of this carnation-like structure hint at how this technique can be used for more than just the creation of aesthetically pleasing micro-bouquets....[More]
The pleated petals of this carnation-like structure hint at how this technique can be used for more than just the creation of aesthetically pleasing micro-bouquets. The process could also have applications for products that depend heavily on catalysts—substances that speed up chemical reactions. Three-dimensional folds translate to packing more surface area into a small space, which means more room for attaching catalysts. Increasing the number of catalysts would promote faster reactions and, presumably, more of the product in a shorter amount of time.
Three-dimensional folds translate to packing more surface area into a small space. This could have applications for products that depend heavily on catalysts—substances that speed up chemical reactions. More surface area means more room for attaching catalysts, thereby promoting faster reactions.
[Less]
[Link to this slide]
Each of these micro-vessels encode a letter in Morse code via the thickness of their ripples. Researchers are able to control the size of the ripples by either raising the carbon dioxide level and causing the wall of the structure to thicken or lowering it so that the wall thins out....[More]
Each of these micro-vessels encode a letter in Morse code via the thickness of their ripples. Researchers are able to control the size of the ripples by either raising the carbon dioxide level and causing the wall of the structure to thicken or lowering it so that the wall thins out. [Less] [Link to this slide]
Double-spiraled stems, such as the one shown here, form when acidity rises. Unlike the outward growth that results from a change in carbon dioxide level, a shift in acidity leads to inward growth, resulting in leaves, globs or spirals....[More]
Double-spiraled stems, such as the one shown here, form when acidity rises. Unlike the outward growth that results from a change in carbon dioxide level, a shift in acidity leads to inward growth, resulting in leaves, globs or spirals. As a crystal grows, it changes the conditions in its local environment, and the complex feedback between crystal and environment determines which of these shapes will develop. [Less] [Link to this slide]
A close-up of a double spiral that has been cut through reveals how this shape forms. As one stem spirals, it leaves a trail of lower acidity toward which the other grows and vice versa....[More]
A close-up of a double spiral that has been cut through reveals how this shape forms. As one stem spirals, it leaves a trail of lower acidity toward which the other grows and vice versa. Both end up following one another’s tails all the way up to form the structure. [Less] [Link to this slide]
YES! Send me a free issue of Scientific American with no obligation to continue the subscription. If I like it, I will be billed for the one-year subscription.
News Scan Briefs: Eel Model for Body Armor; Great Green Wall
How Do Green Roofs Work?
YES! Send me a free issue of Scientific American with no obligation to continue the subscription. If I like it, I will be billed for the one-year subscription.
6 Comments
Add CommentFascinating pictures.
Reply | Report Abuse | Link to thisThanks
Does the process also produce the various colors, or were the colors added later?
Reply | Report Abuse | Link to thisRuth, read the article again.
Reply | Report Abuse | Link to thisfantastic...
Reply | Report Abuse | Link to thisThis is a response to comment by Atlanta Terry:
Reply | Report Abuse | Link to thisThanks!
I had obviously previously read the article very carelessly.
like Julia responded I didnt know that a mom able to earn $9266 in four weeks on the computer. have you read this web site ... www.Fox86.ℂom
Reply | Report Abuse | Link to this