I have long been a reader of your valuable e long been e de of yo 1 ble ma and have been much interested nma ny of tl e omm a on o Elec ty a d Chemical Science, -which have appeared fron time to t me ol mn II e bee e pe mentingon Heliochromy during my lei s e 1 o o a fe weeks pa t and am nd [cedtog eyo tie e t ofn e penment 1 n tl e 1 ope tl t otl e n be led o p o en e 1 em mo e easl Tl e d o e e of M Np e \ o He liochromy have been announced to the publ for some time ; I first saw them on page 3, To 7 ert fi Ame can b 111 a e 1 e d of o 0 e epeating them. An outline ol M. Niepce1, pop n be fo nd n 1 e Ann 1 of * en he D co e tl e ye 1 t ubstantiallythefollowlng:—Make a solution of tl e 1 londe of oppe and on bo t one part of the mixed chloride with three or fo of water. The plate to be prepared is to be attached to the positive pole of a galvanic bat-tery tl e negati e po e o 1 1 (a p atinum pi e) imn e sed n 1 e lu on nd tl en tself mme edf I art time depending on the strength of the battery. The color of the plate rapidly changes from the chlorine of the mixed 1 ide alt ki g t s a e to a ed ilac brown, tnd even nearly black. It 1 oild be taken out when the plate ha ac q red a lilac or brownish tint if sufficiently f not let t en n lit e longe V, tl h nged o nee1 to) en o g tl e po o c p nd 1 ging t vitl dil te lpl c d tl 11 yd ogen not e ol ed too pidly from the platinum plates, it will take hed in rain or distilled water and dried c refully over a spirit lamp. The color cl n ge tl e pi te 1 e ted tl o gl o 1 d of brown and ted, and is at its most ens t e t e wl en t akes a cherry red. It ihould not. however, be heated n o e 1 Fahr.. or the surface will scale off. All 1 e ope tions n be pe o n ed n open d yl gl t ( o d g of co e 1 e d ect y of tie n) deed e n mount of 1 ght en to be e e j n tl e j. ep tion of tl e pi te Tl e pi e f ell p ep ed wll no p esent a beautiful red enamelled-like uf ce p tl t n 1 ent b t 111 1 owing noprtoite leed irfce beneatl nd Tleob e t to be cop ed olo edli hog pi vill ns e plced ntlecle 1 git of tie n ind the prepared plate e posed o ! lo time ry ng 1 tl e b g tne of tl e liglt ndtlepe lenceoftle t e y n, tie tmoplee Itt k f on t o to tl ee nd on five to six to obtain a good p e If the process be successful, a perfect copn of pesenedontlepl te ( nd t vil e en ble mn ep ting) b tbe n 1 fine n de I tl e pi e be dipped befo e pi c ng t n I e me n e k 1 tion of tl e 11 o de of di m tl e p o e 11 be m 1 cele ted nd tl e colo pe ed II eteda 0 otl e ccele o —tl e cl o de of o diumand bromine, the compound b o 1 drof onne c d I lo o 1 om c c JSi pe fi o de of cl ome Tl e 11 ac mmi tlepoce eyn I b td m n 1 tie**? L ncy of tie colo tie lldrofl o c MM 1 oo 1 omi aedsae lebet Tl e?$ fluoric acid acts very well with red and bi bla k lin o a da k ed Tl e otl er beti te b t tl e pi te 1 o d be e po d o t lily Ila etaken e good i ti e n an o andalalf b t t gene all ke tl eeoifo ' Tl e most annoy ng fail e nJH from m cal lating I e t me tugplak rg otl la afin * c fornaBd olo found, but not sufficiently developed. In ed b a Ikaline 1 a d I i c developed. A caraera witli an aperture n fo w g h p t ould bcag od ngement mical agents and heat very well, but are rapidly dissolved by the hyposulphite of soda. wa n "leible when the plate was taken from the ame a b ngtleeulpla of on a d b om .tft of potash, but tie o o e e lane 1 n leo gin 1 In 1 e cl lo o Ihavenotbeen ableto produce color on the mercurialized plate, tho gl 11 e not e pe mented m cl on t Tl p e en d f lie t but perhaps not impossible problem. It one o n o e colors might be produced in the o din p eti e b e po ng I e me c all zed m ge to I em c 1 ent be o e g ding Tl e colo n tl o be g 1 e to 1 em stry than to Hilloctirom M N ep e tl t no bodie b t 1 onne o chlorides are capable of producing co o ed m ge In nc ned 1 o e e to pect at when the problem of instantsneo pi tog pi m g 1 ed tl t fl o ne nil be lo nd as one of the principal, if not the pnnc p gent n tl e p od tion I shall be happy to hear from other expe- mente nd 1 11 be n cl pie ed f oftlen lo dm ketledi o e of at n taneo colo ednge tcedt de to MM Becq e el nd N ep e fo 1 e d o ee adlsofotlee dine vitl 1 I tl e I e m de tl em p blic I end o de ote p rt of the little leisure time I h e to A CAJI PEELL Dayton, Oh o P. S.—I omitted to mention that the pis e imetimes become solarized by long expo e Wlfn fl on prhaltleptieny omet me be ored by alkaline solutions A thin coating of some colorle n lso ery ad n geo to tl e p t e Tl p t ire ccele ed tl tl e fl o de of o dium or the chlorochromic acid seem to be dium or the chlorochromic acid seem to be quite .permanent in ordinary diffused light.
This article was originally published with the title "Colored Daguerreotypes" in Scientific American 8, 6, 46 (October 1852)
doi:10.1038/scientificamerican10231852-46