Lectures on Chemistry.—No. 2

[Reported expressly for the Scientific American]


On supporting science journalism

If you're enjoying this article, consider supporting our award-winning journalism by subscribing. By purchasing a subscription you are helping to ensure the future of impactful stories about the discoveries and ideas shaping our world today.


[An abstract of a Lecture on Water, delivered before the Mechanics' Institute, at Cincinnati, Ohio, by Prof. Chas. W. Wright.] Water is composed of oxygen and hydrogen combined, in the proportions of eight parts of the former to one of the latter, by weight, and by volume, of two of hydrogen and one of oxygen, or in 100 parts of water there are 11-1 of hydrogen united to 88'9 01 oxygen. Water plays the part of a base towards acids, and of an acid towards bases: thus, when it combines with sulphuric acid it is termed the sulphate of water, and when it unites with lime the compound takes the name of the hydrate of lime. By most chemists, water is looked upon'as a metallic oxide or rust, hydrogen being considered a metal; and Dr. Kane has shown that there is the closest similarity between the oxydes of zinc and copper, and water, which is the oxyde of the metal hy drogen. In some quantities, water is transparent and colorless, but in large volumes it is blue by reflected, -and green by transmitted light. The s0lvent powers of water exceed that of any other liquid. As a generating, this solvent power is increased by heat, as regards solids, but the reverse is the case as regards gases. Under great pressure, water will dissolve bodies, as glass, which are insoluble in it at a moderate heat and pressure. Walter, like most 0ther bodies, contracts on the abstraction of heat ; but when its temperature is reduced to 39", the 1o8s cf heat, instead of causing contraction, increases its volume, and hence, at '390, water is at its point of maximum density, and the addition or abstraction of heat will augment its volume. From 39° to many degrees below the freezing point o f water, it expands, and hence ice is ofless specific gravity than water, and floats upon it. The impor- tan®e of this, in preventing the consolidation 0f large bodies of water, is evident. At 32°, if water be agitated, it freezes, but ifit be under great pressure, which resists its expansion, it will not consolidate at that degree of temperature, and the same is true in regard to other substances that expand in congealing. Water, in the act of freezing, parts with all matter which it holds in solution and suspension, and hence the water of the ocean is rendered sweet and drinkable by being frozen. On the same principle, ice, which is cut from pools that are stagnant in summer, is fit for d0mestic use. Ice which contains air and 0ther impurities, mechanically suspended in it, thaws much sooner than that which is free from such contamination. In passing into the condition of water, ice conceals, or renders latent, 140” of heat, and water, in the act of freezing, imparts the same quantity of heat to surrounding bodies. Hence, freezing is a, heating process, and thawing a cooling one; for the same reason laige masses of snow and ice are never melted suddenly, and inundations are less frequent than they otherwise would be. When the mercury in the barometer stands at 30 inches, water boils at 212° in a metallic vessel, but in a smooth glass vessel it requires 214° to make water boil. Water, free from air and other impurities, does not boil at 212", but when it reaches a temperature of '270° it explodes violently. This can best be shown by melting ice under the surface ol oil, which prevents the absorption of air, when at 270° it explodes. A diminution of atmospheric pressure reduces the boiling point, and if it be increased the reverse is the case. Water evaporates at all temperatures, even in the condition of ice it assumes the gaseous form, with- 0ut passing into the intermediate condition of a liquid. This is seen when articles of clothing are hung out to dry in winter, when they freeze and dry without thawing, and the same thing is seen when the mud in the streets freezes and dries, although the temperature may remain below 32° In boiling and passing into the condition of steam, water takes up and conceals 1000'” of heat; and when this fluid is boiled violently, it is no hotter than when it boils . slowly, lrom the fact of the ad. ditional heat being carried offby.the steam,and the temperature of the water, under ordinary atmospheric pressure never rises higher than 212". The knowledge of this fact is of great importance in domestic economy; tor water, boiling gently, will accomplish as much in culinary operations as when the ebullition is violent. The latent heat carried off by steam has much to do with regulating the temperature of the earth, and also that of the bodies of animals, for the same law holds at low as well as at high temperatures. At 212° the elastic force of steam is equal to a pressure of one atmosphere ; at 250'” the pressure is doubled; and at a temperature of 500° we have a pressure equal to 50 atmospheres. Thus we sea, contrary to' the common impression, it does not require twice the amount ot heat to double the pressure. The action of water on metallic vessels is not a little singuiar: thus, it the water be pure, its action is more corrosive to lead aijd zinc than if it have mineral matter in solution. The Water of the oeean, at great depths, has a different action upon me talsfrom what it has at the surface. Ali the surface, according to the experiments t;f Dr. A. A. Hayes, metals are converted into 6xydes and chlorides, but at great depths the same metals are converted into the sulphurets.

Scientific American Magazine Vol 8 Issue 15This article was published with the title “Lectures on Chemistry.—No. 2” in Scientific American Magazine Vol. 8 No. 15 (), p. 114
doi:10.1038/scientificamerican12251852-114

It’s Time to Stand Up for Science

If you enjoyed this article, I’d like to ask for your support. Scientific American has served as an advocate for science and industry for 180 years, and right now may be the most critical moment in that two-century history.

I’ve been a Scientific American subscriber since I was 12 years old, and it helped shape the way I look at the world. SciAm always educates and delights me, and inspires a sense of awe for our vast, beautiful universe. I hope it does that for you, too.

If you subscribe to Scientific American, you help ensure that our coverage is centered on meaningful research and discovery; that we have the resources to report on the decisions that threaten labs across the U.S.; and that we support both budding and working scientists at a time when the value of science itself too often goes unrecognized.

In return, you get essential news, captivating podcasts, brilliant infographics, can't-miss newsletters, must-watch videos, challenging games, and the science world's best writing and reporting. You can even gift someone a subscription.

There has never been a more important time for us to stand up and show why science matters. I hope you’ll support us in that mission.

Thank you,

David M. Ewalt, Editor in Chief, Scientific American

Subscribe