Super-Stretchy Hydrogel Can Take a Hit

A polymer network made of alginate and polyacrylamide is the most resilient yet and could be used in replacement cartilage or scaffolding for artificial organs

By Katharine Sanderson & Nature magazine

Join Our Community of Science Lovers!

From Nature magazine

Your eyes aren’t deceiving you — you just watched a metal ball bounce off a sliver of jelly. But you wouldn’t put this jelly in a sherry trifle: it is a sophisticated hydrogel developed by Zhigang Suo, a materials engineer at Harvard University in Cambridge, Massachusetts, and his colleagues¹.

A hydrogel is a network of polymers that soaks up lots of water to form a jelly-like material. But most shatter easily and don’t stretch far without breaking. Some of the toughest hydrogels are used to make soft contact lenses, and researchers want to make them more robust, for use in replacement cartilage or as scaffolds for growing artificial organs.

On supporting science journalism

If you're enjoying this article, consider supporting our award-winning journalism by subscribing. By purchasing a subscription you are helping to ensure the future of impactful stories about the discoveries and ideas shaping our world today.

Suo’s hydrogel is made from a mixture of two polymers — alginate and polyacrylamide. Each polymer forms networks using different types of chemical bond: alginate molecules are linked together by ionic bonds, and polyacrylamide molecules by stronger covalent bonds. When the gel is stretched, hit or torn, the ionic bonds can break and reform throughout the material, dissipating energy over a wide area and causing fewer of the covalent bonds to be irreversibly ruptured. The covalent bonds hold the material together, allowing it to spring back to its original shape.

Separately, the two polymers can each form normal hydrogels — but when they are mixed together, the resulting material is far stronger than its constituent parts. The energy needed to fracture the combination hydrogel is on a par with that for natural rubber at 9,000 joules per square metre, and the gel can be stretched to 20 times its original length without breaking. “You can’t even tear it apart with your hands,” says Suo.

This article is reproduced with permission from the magazine Nature. The article was first published on September 5, 2012.

Subscribe to Support Independent Journalism

Great science journalism requires human expertise, time, effort and creativity. And it costs money. That’s why I and the journalists here at Scientific American hope you’ll join our community.

When you subscribe, you are supporting staff and freelance journalists who are passionate about telling science stories that are true, important and compelling. Our editors and reporters are often experts in their fields, which means they understand the nuances of big discoveries and can untangle the breakthroughs from the hype. With a subscription, you are also supporting rigorous fact-checking to ensure the words we publish are precise and accurate. And you’re supporting original illustrations, graphics and photos that bring you closer to an advanced laboratory, an ice sheet in Antarctica or a space mission in orbit. You’re helping us craft other types of high-quality journalism as well: Our newsletters are carefully written, edited and curated by staffers you have or will come to know and love. Our Science Quickly podcast is based on original reporting, collaboration with editors and scientists and exacting production.

Subscriptions keep this engine running so we can continue to deliver thoughtful, rigorous and independent science journalism to you. In an era of viral misinformation, this work is crucial. If you value what we do, I hope you’ll consider joining us as a subscriber

Thank you,

Jeanna Bryner, Editor in Chief, Scientific American