Solar cells are picky. If an incoming photon has too little energy, the cell won’t absorb it. If a photon has too much, the excess is wasted as heat. No matter what, a silicon solar cell can never generate more than one electron from a single photon. Such harsh quantum realities severely limit the conversion efficiency of photovoltaic cells, and scientists have spent decades looking for work-arounds.
Now, researchers at the Massachusetts Institute of Technology’s Center for Excitonics have published a compelling case that the key to greater solar efficiency might be an organic dye called pentacene. In today’s issue of Science Daniel Congreve, Jiye Lee, Nicholas Thompson, Marc Baldo and six others show that a photovoltaic cell based on pentacene can generate two electrons from a single photon—more electricity from the same amount of sun. Scientists have suspected for some time that this might work; today’s paper is proof of concept.
The key is a phenomenon called singlet-exciton fission, in which an arriving photon generates two “excitons” (excited states) that can be made to yield two electrons. Previous researchers had accomplished similar tricks using quantum dots (tiny pieces of matter that behave like atoms) and deep-ultraviolet light. “What we showed here,” Baldo says, in addition to using visible light, “is that [this process] works very, very effectively in organic materials.”
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Why it works is still not particularly clear, and for now, the pentacene cell works only with an extremely narrow band of visible light. But Baldo says it should be possible to create a pentacene coating for silicon solar cells that boosts the total conversion efficiency from today’s 25 percent to a shade over 30 percent—a significant jump. Developing that technology is the obvious next step. “Can we apply this thing as a coating on silicon?” Baldo says. “If we can do that, it would have a pretty major impact on solar cell technology.”
